The best guide is probably this one -
www.microsoft.com/.../relationship.mspx
The bottom line is WSS is included in Windows Server 2003 and is focused on
group collaboration - document sharing, meetings, etc. portal is a product on
its own, is built using WSS as the platform, but it focsed on more tradiitional
portal activities (exposing information to large, targetted audiences,
enterprised search, application integration, etc).