The site definition used when building a site isn't available anywhere in
the user interface. The only other way to get the underlying site
definition, without writing code, would be to do the following:
1. Save the site as a template
2. Download the template to your local harddrive
3. Change the extension from .stp to .cab (the .stp is a normal
compressed cabinet file)
4. Open the .cab file and extract the manifest.xml file to your hard
drive
5. Open the manifest.xml file in an editor and find the TemplateID and
Configuration elements. These reference a specific site definition value
listed in one of the Webtemp.xml files stored in the 12 hive at
template/1033/xml.
Personally, I find it easier to write a quick command line utility program.
Again, these values will only give you the base site definition from which
the site was built, not the site template if one was used. There is no way
that I know of to get the site template (.STP) file used to create an
existing site.