You seem to have two problems here so let's work them out one at a time.
First, you say "image is not visible". Are you talking about your own images
or something you're trying to reference in SharePoint or ...? Quickest thing
to do is to look at the rendered source in the browser (right click, View
Source) of the page of the app. Look for your image and see what the url
it's referencing is.
As for the CSS, the article talks about how to create an application to run
under the SharePoint context but until you put anything "SharePointy" on the
page (like a SharePoint Web Control) it's just an ASP.NET application so
it's not magically going to use the SharePoint CSS files (if that's what
you're trying to get). Also you'll need to tag your own controls with the
SharePoint class names in order to pick up the styles (after you add the CSS
file to your page).